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" "What happens... in a steam-engine... ? The caloric developed in the furnace by the effect of the combustion traverses the walls of the boiler, produces steam, and in some way incorporates itself with it. The latter carrying it away, takes it first into the cylinder, where it performs some function, and from thence into the condenser, where it is liquefied by contact with the cold water... [T]he cold water of the condenser takes possession of the caloric... It is heated by the intervention of the steam as if it had been placed directly over the furnace. The steam is here only a means of transporting the caloric.
(French: [kaʁno]; 1 June 1796 – 24 August 1832) was a French military engineer and physicist, often described as the "father of thermodynamics". In his only publication, the 1824 monograph , Carnot gave the first successful theory of the maximum efficiency of s. Carnot's work attracted little attention during his lifetime, but it was later used by Rudolf Clausius and Lord Kelvin to formalize the second law of thermodynamics and define the concept of .
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The phenomenon of the production of motion by heat has not been considered from a sufficiently general point of view. We have considered it only in machines... [for which] the phenomenon is... incomplete. It becomes difficult to recognize its principles and study its laws. ...[T]he principle of the production of motion by heat... must be considered independently of any mechanism or... particular agent. It is necessary to establish principles applicable not only to steam-engines but to all imaginable heat-engines, whatever the working substance and whatever the method by which it is operated.
Wherever there exists a difference of temperature... it is possible to have also the production of impelling power. ...All substances in nature can be employed for this purpose, all are susceptible of changes of volume, of successive contractions and dilatations, through the alternation of heat and cold. All are capable of overcoming in their changes of volume certain resistances... A solid... A liquid... An aeriform fluid... If it is enclosed in an expansible space, such as a cylinder provided with a piston, it will produce movements of great extent. Vapors of all substances capable of passing into a gaseous condition, as of , of mercury, of , etc., may fulfil the same office as vapor of water. ...Most of these... have been proposed, many even have been tried, although... without remarkable success.