J. R. Partington Quotes

Some recent short publications on Chinese gunpowder and firearms are misleading... I have had valuable assistance from Dr. J. Needham... If the dates of the texts are correct, the discovery of the use of saltpetre in explosives and the development of gunpowder are to be sought in China from the eleventh century. The history of gunpowder is associated with that of saltpetre, no comprehensive account of which was available.

As an instance of the remarkably far-reaching effect which a single mathematico-physical concept has had upon the development of chemical theory, one has but to recall the state of chemistry just before the revival of Avogadro's law by Cannizzaro, to be impressed by its confusion. Relying solely upon their "chemical instinct," the leaders of the various schools of chemical thought had developed each his own theoretical system. ...a host of ...conceptions strove for supremacy. The strife was stilled, order and unity were restored, as soon as Avogadro's great idea was seen in its true light, and the concept of the molecule was introduced into chemistry. A formula which had required pages of reasoning from a purely chemical standpoint to establish, and that insecurely, was fixed by a single numerical result.

In early physical systems we have optics dealing with phenomena perceived by the eye; acoustics treating of auditory percepts, and so on. The subjective concepts of "tone" and "colour" have now been replaced by the objectified concepts of frequency of vibration; and wave-length. The object of this process of elimination is, according to Planck, the striving towards a unification of the whole theoretical system, so that it shall be equally significant for all intelligent beings.

To a person whose experience has never been brought into relation with the object sulphur, the name signifies nothing; to the scientist... his concept involves the ideas of specific gravity, crystalline form, element, atom, and the like, derived from past experiences. His concept is distinguished from the other by involving... number or quantity.

The statement of a law of nature involves the formation of a concept, or general idea, in which the likenesses of phenomena are collected, and the differences, in so far as they are not intimately involved in the nature of the case, are eliminated.

If the present volume will help towards the comprehension of the fundamental principles on which the science of thermodynamics rests, and also serve to bring home the importance of a knowledge of these principles in the suggestion and interpretation of experimental work, the purpose which has been kept in view during its preparation will have been amply fulfilled. In any case, it is hoped that neither the extreme view that thermodynamic principles alone suffice in the construction of a systematic physical or chemical science, nor the equally mistaken opinion that they are of little practical utility to the experimental worker, can fairly result from its study.

From the time when Guldberg and Waage gave quantitative form to the speculations of the physicist Berthollet, a clear conception of chemical equilibrium, in sharp contrast to an anthropomorphic theory of affinity dating back to Hippocrates and Barchausen, has yielded rich and abundant fruit.

The extension of Black's method by the physicist Lavoisier led to the downfall of the purely qualitative theory of phlogiston, and gave to chemistry the true methods of investigation, and its first great quantitative law—the law of conservation of matter.

Disagreement between theory and experiment has proved a most potent agent in broadening theoretical views, and in making clear the necessity for new concepts or hypotheses.

Wenzel and Richter, the latter... of most pronounced mathematical temperament, laid the foundations of stoichiometry, or "the art of measuring the chemical elements".

The first clear expression of the idea of an element occurs in the teachings of the Greek philosophers. ...Aristotle ...who summarized the theories of earlier thinkers, developed the view that all substances were made of a primary matter... On this, different forms could be impressed... so the idea of the transmutation of the elements arose. Aristotle's elements are really fundamental properties of matter... hotness, coldness, moistness, and dryness. By combining these in pairs, he obtained what are called the four elements, fire, air, earth and water... a fifth, immaterial, one was added, which appears in later writings as the quintessence. This corresponds with the ether. The elements were supposed to settle out naturally into the earth (below), water (the oceans), air (the atmosphere), fire and ether (the sky and heavenly bodies).

Dalton, the mathematical tutor, following up the lead of Newton, combined the whole of the results of quantitative measurement which had accumulated up to his time, in a comprehensive theory, based on the concept of the chemical atom.

The fundamental materials from which we construct our picture of the universe may appear in different shapes, but there is really very little discontinuity between what seem at first sight very different views.

The earliest chemical theory was qualitative in the strictest sense; the so-called Aristotelean doctrine of the four elements assumed that air, water, earth, and fire, were qualities impressed on a primal matter; and the changes of material bodies were explained by the assumption that properties could be taken up by, and impressed upon, or removed from, the base-stuff. Transmutation as a possibility followed at once, and centuries of vain endeavour were required to impress the fact of its impossibility, leading to the true concept of element.

We find Theophrastus (315 B.C.) describing... the manufacture of white lead... "lead is placed in an earthen vessel over sharp vinegar, and after it has acquired some thickness of a kind of rust... they open the vessels and scrape it off. ...repeating over and over again... til it is wholly gone. What has been scraped off they then beat to a powder and boil with water for a long time, and what at last settles to the bottom is white lead.