The laws of thermodynamics, as empirically determined, express the approximate and probable behavior of systems of a great number of particles, or, m… - Josiah Willard Gibbs

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The laws of thermodynamics, as empirically determined, express the approximate and probable behavior of systems of a great number of particles, or, more precisely, they express the laws of mechanics for such systems as they appear to beings who have not the fineness of perception to enable them to appreciate quantities of the order of magnitude of those which relate to single particles, and who cannot repeat their experiments often enough to obtain any but the most probable results.

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About Josiah Willard Gibbs

Josiah Willard Gibbs (February 11 1839 – April 28 1903) was an American theoretical physicist, chemist and mathematician. One of the greatest American scientists of all time, he devised much of the theoretical foundation for chemical thermodynamics, as well as physical chemistry and statistical mechanics.

Also Known As

Alternative Names: J. Willard Gibbs Josiah W. Gibbs Gibbs
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In all these papers we see a love of honest work, an aversion to shams, a caution in the enunciation of conclusions, a distrust of rash generalizations and speculations based on uncertain premises. He was never anxious to add one more guess on doubtful matters in the hope of hitting the truth, or what might pass as such for a time, but was always ready to take infinite pains in the most careful testing of every theory. With these qualities was united a modesty which forbade the pushing of his own claims and desired no reputation except the unsought tribute of competent judges.

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