In every previous application of the quantum law, Planck's law, that the energy is h [Planck's constant] times the frequency, had been used to deduce… - James Hopwood Jeans

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In every previous application of the quantum law, Planck's law, that the energy is h [Planck's constant] times the frequency, had been used to deduce the energy of a quantum when the frequency of the radiation was already known. In the present case the formula was used the other way; the energy of the emitted photon was known to begin with, and the formula was utilized to deduce its frequency. The frequencies calculated in this way are found to agree completely and exactly with those of the spectrum of hydrogen.

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About James Hopwood Jeans

Sir James Hopwood Jeans (11 September 1877 – 16 September 1946) was a British physicist, astronomer and mathematician.

Also Known As

Alternative Names: James Jeans Sir James Jeans Sir James Hopwood Jeans James H. Jeans James H Jeans J. H. Jeans J.H. Jeans J H Jeans
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The classical mechanics had envisaged the world constructed of matter and radiation, the matter consisting of atoms and the radiation of waves. Planck's theory called for an atomicity of radiation similar to that which was so well established for matter. It supposed that radiation was not discharged from matter in a steady stream like water from a hose, but rather like lead from a machine-gun; it came off in separate chunks which Planck called quanta. This... carried tremendous philosophical consequences.

Bohr had... discovered that the frequencies corresponding to very large integers could be calculated accurately from the classical mechanics; they were simply the number of times that an ordinary electron would complete the circuit of its orbit in one second when it was at a very great distance from the nucleus of the atom to which it belonged. This could only mean that when an electron receded to a great distance from the nucleus of its atom, it not only assumed the properties of an ordinary electron, but also behaved as directed by the classical mechanics. Yet the classical mechanics failed completely for the calculation of frequencies corresponding to small orbits.

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The main result reached by the new theory was that the classical mechanics can be made to account for the whole range of spectral phenomena, provided entirely new meanings are given to such symbols as p and q which had hitherto been taken to describe the position and motion of the electron. ...The most significant of the new properties is that the product pq is no longer the same as the product qp - in other words the order in which the two factors are multiplied together is no longer a matter of indifference. The difference between pq and qp is found to be always the same, being Planck's constant h multiplied by a numerical multiplier.

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