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" "We point out that not every reactant is completely consumed in a chemical reaction, and that the limiting reactant determines the maximum theoretical yield; the percentage yield may be somewhat less.
David William Oxtoby (born October 17, 1951) is an American academic who served as the ninth president of Pomona College. He held the position from July 1, 2003, to July 1, 2017. A theoretical chemist, he received his bachelor's degree in chemistry and physics at Harvard University (summa cum laude) and his PhD in chemistry in 1975 from the University of California, Berkeley. Prior to his appointment at Pomona College, he was the dean of the physical sciences division at the University of Chicago.
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The central idea of quantum theory is that energy, like matter, is not continuous but it exists only in discrete packets. Discreteness of matter and charge on the microscopic scale seems entirely reasonable and familiar to us, based on the modern picture of atomic structure. But, the idea that energy also exists only in discrete chunks is contrary to our experience of the macroscopic world. The motions of a soccer ball rolling up and down the sides of a gully involve arbitrary amounts of kinetic and potential energy; nothing in ordinary human experience suggests that the energy of a system should change abruptly by “jumps.” Understanding quantum mechanics requires that we develop a new kind of physical intuition, based on the results of experiments that are impossible to understand using classical mechanics. These results are completely divorced from ordinary human experience in the macroscopic world around us, and our physical intuition from the macroscopic world cannot be transferred to the quantum domain. We must resist the urge to interpret these quantum results in terms of ordinary experience.
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Quantum mechanics explains the physical stability of the atom by predicting its allowed discrete energy levels and defining the wave functions (also called atomic orbitals) associated with each energy level. The orbitals determine the probability density for finding the electrons at particular locations in the atom when the electrons are in a specific quantum state.