On the one hand, the student has been informed by some writers that the only certain way lies in the use of the entropy-function and the thermodynami… - J. R. Partington

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On the one hand, the student has been informed by some writers that the only certain way lies in the use of the entropy-function and the thermodynamic potentials; on the other hand, he is told with equal authority that the method used by the original investigators has been the consideration of cyclic processes, and that the former method is nothing but a mathematical (perhaps unnecessary) refinement of the results obtained by the latter. These extreme attitudes appear to me to be unfortunate, and more especially when one observes the physical clearness introduced by the use of cyclic processes, but at the same time remembers that most of the results obtained by separate investigators using cyclic processes had, with a great many more, previously been found by J. Willard Gibbs by means of a purely analytical method.

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About J. R. Partington

James Riddick Partington (30 June 1886 – 9 October 1965) was a British chemist, mathematician, historian of chemistry, scholar, author and teacher. He was a fellow and council member of the Chemical Society of London and the first president of the Society for History of Alchemy and Early Chemistry.

Also Known As

Alternative Names: James Riddik Partington J R Partington James R. Partington James R Partington James Riddick Partington
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It is clear, however, that the distinguishing mark of the whole development of theoretical chemistry and physics is the elimination of the anthropomorphic elements, especially specific sense-impressions, from the concepts. This process is called by Prof. M. Planck the objectification of the physical system.

From the time when Guldberg and Waage gave quantitative form to the speculations of the physicist Berthollet, a clear conception of chemical equilibrium, in sharp contrast to an anthropomorphic theory of affinity dating back to Hippocrates and Barchausen, has yielded rich and abundant fruit.

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There are not wanting, even to-day, chemists who advocate "purely chemical" methods in chemistry, and cannot appreciate the value of physical evidence in conjunction with mathematical calculations. We can only hope that their number is decreasing exponentially with time.

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