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" "We want first to solve the problem... namely to calculate the probability of state distributions from the number of different distributions. We want first to treat as simple a case as possible, namely a gas of rigid absolutely elastic spherical molecules trapped in a container with absolutely elastic walls. Even in this case, the application of is not easy. The number of molecules is not infinite... yet the number of velocities each molecule is capable of is effectively infinite... to facilitate understanding, I will... consider a limiting case.
Ludwig Eduard Boltzmann (February 20, 1844 – September 5, 1906) was an Austrian physicist and philosopher famous for his founding contributions in the fields of statistical mechanics and statistical thermodynamics. He was one of the most important advocates for atomic theory which was still highly controversial.
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We assume initially, each molecule is only capable of assuming a finite number of velocities...<math>0, \frac{1}{q},\frac{2}{q},\frac{3}{q},...\frac{p}{q}</math>where <math>p</math> and <math>q</math> are arbitrary finite numbers. ...but after the collision both molecules still have one of the above velocities ...the actual problem to be solved is re-established by letting p and q go to infinity.
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I am conscious of being only an individual struggling weakly against the stream of time. But it still remains in my power to contribute in such a way that, when the theory of gases is again revived, not too much will have to be rediscovered. Thus in this book [this Part] I will now include the parts that are the most difficult and most subject to misunderstanding, and give (at least in outline) the most easily understood exposition of them.